Describe the fundamental properties of solutionsCalculate solution concentrations using molarityPerform dilution calculations using the dilution equation

In preceding sections, we focused on the composition of substances: samples of matter that contain only one type of element or compound. However, mixtures—samples of matter containing two or more substances physically combined—are more commonly encountered in nature than are pure substances. Similar to a pure substance, the relative composition of a mixture plays an important role in determining its properties. The relative amount of oxygen in a planet’s atmosphere determines its ability lớn sustain aerobic life. The relative amounts of iron, carbon, nickel, & other elements in steel (a mixture known as an “alloy”) determine its physical strength và resistance khổng lồ corrosion. The relative amount of the active ingredient in a medicine determines its effectiveness in achieving the desired pharmacological effect. The relative amount of sugar in a beverage determines its sweetness (see Figure 1). In this section, we will describe one of the most common ways in which the relative compositions of mixtures may be quantified.

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Figure 1. Sugar is one of many components in the complex mixture known as coffee. The amount of sugar in a given amount of coffee is an important determinant of the beverage’s sweetness. (credit: Jane Whitney)Solutions

We have previously defined solutions as homogeneous mixtures, meaning that the composition of the mixture (and therefore its properties) is uniform throughout its entire volume. Solutions occur frequently in nature and have also been implemented in many forms of manmade technology. We will explore a more thorough treatment of solution properties in the chapter on solutions & colloids, but here we will introduce some of the basic properties of solutions.

The relative amount of a given solution component is known as its concentration. Often, though not always, a solution contains one component with a concentration that is significantly greater than that of all other components. This component is called the solvent & may be viewed as the medium in which the other components are dispersed, or dissolved. Solutions in which water is the solvent are, of course, very common on our planet. A solution in which water is the solvent is called an aqueous solution.

A solute is a component of a solution that is typically present at a much lower concentration than the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) & concentrated (of relatively high concentration).

Concentrations may be quantitatively assessed using a wide variety of measurement units, each convenient for particular applications. Molarity (M) is a useful concentration unit for many applications in chemistry. Molarity is defined as the number of moles of solute in exactly 1 liter (1 L) of the solution:

### Example 1

Calculating Molar ConcentrationsA 355-mL soft drink sample contains 0.133 mol of sucrose (table sugar). What is the molar concentration of sucrose in the beverage?

SolutionSince the molar amount of solute and the volume of solution are both given, the molarity can be calculated using the definition of molarity. Per this definition, the solution volume must be converted from mL to lớn L:

M = frac extmol solute extL solution = frac0.133 ; extmol355 ; extmL imes frac1 ; extL1000 ; extmL = 0.375 ; M

Check Your LearningA teaspoon of table sugar contains about 0.01 mol sucrose. What is the molarity of sucrose if a teaspoon of sugar has been dissolved in a cup of tea with a volume of 200 mL?

### Example 2

Deriving Moles and Volumes from Molar ConcentrationsHow much sugar (mol) is contained in a modest sip (~10 mL) of the soft drink from Example 1?

SolutionIn this case, we can rearrange the definition of molarity lớn isolate the quantity sought, moles of sugar. We then substitute the value for molarity that we derived in Example 1, 0.375 M:

M = frac extmol solute extL solution extmol solute = M imes extL solution

extmol solute = 0.375 ;frac extmol sugar extL imes (10 ; extmL imes frac1 extL1000 ; extmL) = 0.004 ; extmol sugar

Check Your LearningWhat volume (mL) of the sweetened tea described in Example 1 contains the same amount of sugar (mol) as 10 mL of the soft drink in this example?

### Example 3

Calculating Molar Concentrations from the Mass of SoluteDistilled trắng vinegar (Figure 2) is a solution of acetic acid, CH3CO2H, in water. A 0.500-L vinegar solution contains 25.2 g of acetic acid. What is the concentration of the acetic acid solution in units of molarity?

Figure 2. Distilled trắng vinegar is a solution of acetic acid in water.

SolutionAs in previous textbox shaded, the definition of molarity is the primary equation used lớn calculate the quantity sought. In this case, the mass of solute is provided instead of its molar amount, so we must use the solute’s molar mass to lớn obtain the amount of solute in moles:

M = frac extmol solute extL solution = frac25.2 ; extg CH_3 extCO_2 extH imes frac1 ; extmol CH_2 extCO_2 extH60.052 ; extg CH_2 extCO_2 extH0.500 ; extL solution = 0.839 ;M
= l} M & frac extmol solute extL solution = 0.839;M \<1em> M & frac0.839 ; extmol solute1.00 ; extL solution endarray

Check Your LearningCalculate the molarity of 6.52 g of CoCl2 (128.9 g/mol) dissolved in an aqueous solution with a total volume of 75.0 mL.

### Example 4

Determining the Mass of Solute in a Given Volume of SolutionHow many grams of NaCl are contained in 0.250 L of a 5.30-M solution?

SolutionThe volume & molarity of the solution are specified, so the amount (mol) of solute is easily computed as demonstrated in Example 2:

M = ;frac extmol solute extL solution extmol solute = M imes extL solution extmol solute = 5.30 ;frac extmol NaCl extL imes 0.250 ; extL = 1.325 ; extmol NaCl

Finally, this molar amount is used lớn derive the mass of NaCl:

1.325 ; extmol NaCl imes frac58.44 ; extg NaCl extmol NaCl = 77.4 ; extg NaCl

Check Your LearningHow many grams of CaCl2 (110.98 g/mol) are contained in 250.0 mL of a 0.200-M solution of calcium chloride?

When performing calculations stepwise, as in Example 4, it is important to refrain from rounding any intermediate calculation results, which can lead to rounding errors in the final result. In Example 4, the molar amount of NaCl computed in the first step, 1.325 mol, would be properly rounded lớn 1.32 mol if it were lớn be reported; however, although the last digit (5) is not significant, it must be retained as a guard digit in the intermediate calculation. If we had not retained this guard digit, the final calculation for the mass of NaCl would have been 77.1 g, a difference of 0.3 g.

In addition to retaining a guard digit for intermediate calculations, we can also avoid rounding errors by performing computations in a single step (see Example 5). This eliminates intermediate steps so that only the final result is rounded.

### Example 5

Determining the Volume of Solution Containing a Given Mass of SoluteIn Example 3, we found the typical concentration of vinegar khổng lồ be 0.839 M. What volume of vinegar contains 75.6 g of acetic acid?

SolutionFirst, use the molar mass to lớn calculate moles of acetic acid from the given mass:

Then, use the molarity of the solution khổng lồ calculate the volume of solution containing this molar amount of solute:

extmol solute imes frac extL solution extmol solute = extL solution

extg solute imes frac extmol solute extg solute imes frac extL solution extmol solute = extL solution75.6 ; extg CH_3 extCO_2 extH (frac extmol CH_3 extCO_2 extH60.05 ; extg) (frac extL solution0.839 ; extmol CH_3 extCO_2 extH) = 1.50 ; extL solution

Dilution of Solutions

Dilution is the process whereby the concentration of a solution is lessened by the addition of solvent. For example, we might say that a glass of iced tea becomes increasingly diluted as the ice melts. The water from the melting ice increases the volume of the solvent (water) and the overall volume of the solution (iced tea), thereby reducing the relative concentrations of the solutes that give the beverage its taste (Figure 3).

Figure 3. Both solutions contain the same mass of copper nitrate. The solution on the right is more dilute because the copper nitrate is dissolved in more solvent. (credit: Mark Ott)

Dilution is also a common means of preparing solutions of a desired concentration. By adding solvent lớn a measured portion of a more concentrated stock solution, we can achieve a particular concentration. For example, commercial pesticides are typically sold as solutions in which the active ingredients are far more concentrated than is appropriate for their application. Before they can be used on crops, the pesticides must be diluted. This is also a very common practice for the preparation of a number of common laboratory reagents (Figure 4).

Figure 4. A solution of KMnO4 is prepared by mixing water with 4.74 g of KMnO4 in a flask. (credit: modification of work by Mark Ott)

A simple mathematical relationship can be used to relate the volumes và concentrations of a solution before & after the dilution process. According khổng lồ the definition of molarity, the molar amount of solute in a solution is equal lớn the hàng hóa of the solution’s molarity & its volume in liters:

where the subscripts “1” and “2” refer to the solution before and after the dilution, respectively. Since the dilution process does not change the amount of solute in the solution,n1 = n2. Thus, these two equations may be phối equal khổng lồ one another:

This relation is commonly referred to as the dilution equation. Although we derived this equation using molarity as the unit of concentration và liters as the unit of volume, other units of concentration and volume may be used, so long as the units properly cancel per the factor-label method. Reflecting this versatility, the dilution equation is often written in the more general form:

Use the simulation to lớn explore the relations between solute amount, solution volume, và concentration & to confirm the dilution equation.

### Example 6

Determining the Concentration of a Diluted SolutionIf 0.850 L of a 5.00-M solution of copper nitrate, Cu(NO3)2, is diluted lớn a volume of 1.80 L by the addition of water, what is the molarity of the diluted solution?

SolutionWe are given the volume and concentration of a stock solution, V1 & C1, and the volume of the resultant diluted solution, V2. We need lớn find the concentration of the diluted solution, C2. We thus rearrange the dilution equation in order to isolate C2:

Since the stock solution is being diluted by more than two-fold (volume is increased from 0.85 L to lớn 1.80 L), we would expect the diluted solution’s concentration khổng lồ be less than one-half 5 M. We will compare this ballpark estimate to the calculated result to kiểm tra for any gross errors in computation (for example, such as an improper substitution of the given quantities). Substituting the given values for the terms on the right side of this equation yields:

C_2 = frac0.850 ; extL imes 5.00 frac extmol extL1.80 ; extL = 2.36 ;M

This result compares well khổng lồ our ballpark estimate (it’s a bit less than one-half the stock concentration, 5 M).

Check Your LearningWhat is the concentration of the solution that results from diluting 25.0 mL of a 2.04-M solution of CH3OH to 500.0 mL?

### Example 7

Volume of a Diluted SolutionWhat volume of 0.12 M HBr can be prepared from 11 mL (0.011 L) of 0.45 M HBr?

SolutionWe are given the volume and concentration of a stock solution, V1 & C1, & the concentration of the resultant diluted solution, C2. We need to lớn find the volume of the diluted solution, V2. We thus rearrange the dilution equation in order khổng lồ isolate V2:

Since the diluted concentration (0.12 M) is slightly more than one-fourth the original concentration (0.45 M), we would expect the volume of the diluted solution lớn be roughly four times the original volume, or around 44 mL. Substituting the given values and solving for the unknown volume yields:

V_2 = frac(0.45;M)(0.011 ; extL)0.12 ; MV_2 = 0.041 ; extL

The volume of the 0.12-M solution is 0.041 L (41 mL). The result is reasonable & compares well with our rough estimate.

Check Your LearningA laboratory experiment calls for 0.125 M HNO3. What volume of 0.125 M HNO3 can be prepared from 0.250 L of 1.88 M HNO3?

### Example 8

Volume of a Concentrated Solution Needed for DilutionWhat volume of 1.59 M KOH is required lớn prepare 5.00 L of 0.100 M KOH?

SolutionWe are given the concentration of a stock solution, C1, and the volume and concentration of the resultant diluted solution, V2 & C2. We need to lớn find the volume of the stock solution, V1. We thus rearrange the dilution equation in order khổng lồ isolate V1:

Since the concentration of the diluted solution 0.100 M is roughly one-sixteenth that of the stock solution (1.59 M), we would expect the volume of the stock solution lớn be about one-sixteenth that of the diluted solution, or around 0.3 liters. Substituting the given values và solving for the unknown volume yields:

V_1 = frac(0.100;M)(5.00 ; extL)1.59 ; MV_1 = 0.314 ; extL

Thus, we would need 0.314 L of the 1.59-M solution to prepare the desired solution. This result is consistent with our rough estimate.

Check Your LearningWhat volume of a 0.575-M solution of glucose, C6H12O6, can be prepared from 50.00 mL of a 3.00-M glucose solution?

Key Concepts and Summary

Solutions are homogeneous mixtures. Many solutions contain one component, called the solvent, in which other components, called solutes, are dissolved. An aqueous solution is one for which the solvent is water. The concentration of a solution is a measure of the relative amount of solute in a given amount of solution. Concentrations may be measured using various units, with one very useful unit being molarity, defined as the number of moles of solute per liter of solution. The solute concentration of a solution may be decreased by adding solvent, a process referred khổng lồ as dilution. The dilution equation is a simple relation between concentrations và volumes of a solution before và after dilution.

Key EquationsM = frac extmol solute extL solutionC1V1 = C2V2

### Chemistry end of Chapter Exercises

Explain what changes & what stays the same when 1.00 L of a solution of NaCl is diluted to lớn 1.80 L.What information bởi vì we need to calculate the molarity of a sulfuric acid solution?What does it mean when we say that a 200-mL sample and a 400-mL sample of a solution of salt have the same molarity? In what ways are the two samples identical? In what ways are these two samples different?Determine the molarity for each of the following solutions:

(a) 0.444 mol of CoCl2 in 0.654 L of solution

(b) 98.0 g of phosphoric acid, H3PO4, in 1.00 L of solution

(c) 0.2074 g of calcium hydroxide, Ca(OH)2, in 40.00 mL of solution

(d) 10.5 kilogam of Na2SO4·10H2O in 18.60 L of solution

(e) 7.0 × 10−3 mol of I2 in 100.0 mL of solution

(f) 1.8 × 104 mg of HCl in 0.075 L of solution

Determine the molarity of each of the following solutions:

(a) 1.457 mol KCl in 1.500 L of solution

(b) 0.515 g of H2SO4 in 1.00 L of solution

(c) 20.54 g of Al(NO3)3 in 1575 mL of solution

(d) 2.76 kilogam of CuSO4·5H2O in 1.45 L of solution

(e) 0.005653 mol of Br2 in 10.00 mL of solution

(f) 0.000889 g of glycine, C2H5NO2, in 1.05 mL of solution

Consider this question: What is the mass of the solute in 0.500 L of 0.30 M glucose, C6H12O6, used for intravenous injection?

(a) Outline the steps necessary to answer the question.

Consider this question: What is the mass of solute in 200.0 L of a 1.556-M solution of KBr?

(a) Outline the steps necessary lớn answer the question.

Calculate the number of moles & the mass of the solute in each of the following solutions:

(a) 2.00 L of 18.5 M H2SO4, concentrated sulfuric acid

(b) 100.0 mL of 3.8 × 10−5M NaCN, the minimum lethal concentration of sodium cyanide in blood serum

(c) 5.50 L of 13.3 M H2CO, the formaldehyde used to lớn “fix” tissue samples

(d) 325 mL of 1.8 × 10−6M FeSO4, the minimum concentration of iron sulfate detectable by taste in drinking water

Calculate the number of moles & the mass of the solute in each of the following solutions:

(a) 325 mL of 8.23 × 10−5M KI, a source of iodine in the diet

(b) 75.0 mL of 2.2 × 10−5M H2SO4, a sample of acid rain

(c) 0.2500 L of 0.1135 M K2CrO4, an analytical reagent used in iron assays

(d) 10.5 L of 3.716 M (NH4)2SO4, a liquid fertilizer

Consider this question: What is the molarity of KMnO4 in a solution of 0.0908 g of KMnO4 in 0.500 L of solution?

(a) Outline the steps necessary lớn answer the question.

Consider this question: What is the molarity of HCl if 35.23 mL of a solution of HCl contain 0.3366 g of HCl?

(a) Outline the steps necessary to answer the question.

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Calculate the molarity of each of the following solutions:

(a) 0.195 g of cholesterol, C27H46O, in 0.100 L of serum, the average concentration of cholesterol in human serum

(b) 4.25 g of NH3 in 0.500 L of solution, the concentration of NH3 in household ammonia

(c) 1.49 kilogam of isopropyl alcohol, C3H7OH, in 2.50 L of solution, the concentration of isopropyl alcohol in rubbing alcohol

(d) 0.029 g of I2 in 0.100 L of solution, the solubility of I2 in water at 20 °C

Calculate the molarity of each of the following solutions:

(a) 293 g HCl in 666 mL of solution, a concentrated HCl solution

(b) 2.026 g FeCl3 in 0.1250 L of a solution used as an unknown in general chemistry laboratories

(c) 0.001 mg Cd2+ in 0.100 L, the maximum permissible concentration of cadmium in drinking water

(d) 0.0079 g C7H5SNO3 in one ounce (29.6 mL), the concentration of saccharin in a diet soft drink.

There is about 1.0 g of calcium, as Ca2+, in 1.0 L of milk. What is the molarity of Ca2+ in milk?What volume of a 1.00-M Fe(NO3)3 solution can be diluted khổng lồ prepare 1.00 L of a solution with a concentration of 0.250 M?If 0.1718 L of a 0.3556-M C3H7OH solution is diluted to a concentration of 0.1222 M, what is the volume of the resulting solution?If 4.12 L of a 0.850 M-H3PO4 solution is be diluted to lớn a volume of 10.00 L, what is the concentration of the resulting solution?What volume of a 0.33-M C12H22O11 solution can be diluted to prepare 25 mL of a solution with a concentration of 0.025 M?What is the concentration of the NaCl solution that results when 0.150 L of a 0.556-M solution is allowed to evaporate until the volume is reduced to lớn 0.105 L?What is the molarity of the diluted solution when each of the following solutions is diluted to lớn the given final volume?

(a) 1.00 L of a 0.250-M solution of Fe(NO3)3 is diluted to lớn a final volume of 2.00 L

(b) 0.5000 L of a 0.1222-M solution of C3H7OH is diluted to lớn a final volume of 1.250 L

(c) 2.35 L of a 0.350-M solution of H3PO4 is diluted to lớn a final volume of 4.00 L

(d) 22.50 mL of a 0.025-M solution of C12H22O11 is diluted khổng lồ 100.0 mL

What is the final concentration of the solution produced when 225.5 mL of a 0.09988-M solution of Na2CO3 is allowed to lớn evaporate until the solution volume is reduced lớn 45.00 mL?A 2.00-L bottle of a solution of concentrated HCl was purchased for the general chemistry laboratory. The solution contained 868.8 g of HCl. What is the molarity of the solution?An experiment in a general chemistry laboratory calls for a 2.00-M solution of HCl. How many mL of 11.9 M HCl would be required to make 250 mL of 2.00 M HCl?What volume of a 0.20-M K2SO4 solution contains 57 g of K2SO4?The US Environmental Protection Agency (EPA) places limits on the quantities of toxic substances that may be discharged into the sewer system. Limits have been established for a variety of substances, including hexavalent chromium, which is limited lớn 0.50 mg/L. If an industry is discharging hexavalent chromium as potassium dichromate (K2Cr2O7), what is the maximum permissible molarity of that substance?